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On this page
  • What Is ASA?
  • Printing with ASA: Precision and Preparation
  • Key Settings
  • Adhesion and Warping
  • Challenges
  • Advantages of ASA
  • Limitations of ASA
  • ASA vs. ABS: A Practical Comparison
  • Applications of ASA
  • Requirements to Print ASA

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  1. The Basics
  2. 3D Printing Materials

ASA

Also known as Acrylonitrile Styrene Acrylate

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Last updated 1 month ago

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Acrylonitrile Styrene Acrylate (ASA) has emerged as a superior alternative to ABS in 3D printing, combining durability with exceptional resistance to weathering. Known for its ability to withstand UV exposure, heat, and harsh environments, ASA is the go-to filament for functional parts that thrive outdoors. From automotive components to garden fixtures, ASA bridges the gap between industrial-grade performance and practical printability.

What Is ASA?

ASA is a thermoplastic polymer engineered to excel in outdoor and high-stress environments. Its composition—acrylonitrile for chemical resistance, styrene for rigidity, and acrylate for UV stability—makes it a robust alternative to ABS. Unlike ABS, ASA retains its color and mechanical properties even after prolonged sun exposure, thanks to its UV-resistant acrylic ester elastomer.

Printing with ASA: Precision and Preparation

ASA demands careful calibration to balance adhesion, warping, and layer bonding. Here’s how to optimize your prints:

Key Settings

  • Nozzle Temperature: 240–280°C (start at 250°C and adjust based on filament brand).

  • Bed Temperature: 90–110°C (heated bed essential for adhesion).

  • Print Speed: 35–70 mm/s (slower speeds improve layer bonding).

  • Ambient Temperature: Maintain a draft-free, warm environment or use an enclosed printer (60°C chamber ideal).

Adhesion and Warping

  • Build Plate: Use PEI sheets, BuildTak, or adhesion items such as Magigoo Original for reliable first-layer grip.

  • Enclosure (or warm ambient air): Critical for minimizing warping and cracking, especially in large prints.

  • Cooling: Reduce or disable part cooling fans to prevent rapid cooling and warping.

Challenges

  • Fumes: ASA emits VOCs during printing; ensure proper ventilation or air filtration.

  • Moisture Sensitivity: Store filament in a dry, sealed container to prevent moisture absorption.

  • Stringing: Fine-tune retraction (1–2 mm at 20–30 mm/s) to minimize oozing.

Advantages of ASA

  1. UV Resistance: Retains color and strength under prolonged sun exposure, ideal for outdoor signs, automotive trim, and patio fixtures.

  2. Thermal Stability: Heat deflection temperature of 86–96°C (1.8 MPa) outperforms PLA and rivals ABS.

  3. Mechanical Strength: Tensile strength of 47.1 MPa and impact resistance of 180 J/m (notched) ensure durability in high-stress applications.

  4. Chemical Resistance: Withstands oils, acids, and alkalis, suitable for industrial or automotive parts.

  5. Post-Processing: Smoothable with acetone vapor for a polished finish, though should be taken with extreme caution due to the flammability of acetone.

Limitations of ASA

  1. Print Complexity: Requires warm ambient air, heated bed, and precise temperature control.

  2. Fume Management: Strong odor during printing necessitates ventilation.

  3. Not Food-Safe: Unsuitable for kitchenware or medical applications.

  4. Material Sensitivity: Prone to warping if printed in humid or drafty environments.

ASA vs. ABS: A Practical Comparison

Property
ASA
ABS

UV Resistance

Excellent

Poor

Heat Resistance

86–96°C (HDT)

100–110°C (HDT)

Impact Strength

180 J/m (Notched)

200 J/m (Notched)

Print Difficulty

Moderate

Challenging

Outdoor Use

Ideal

Not Recommended

Applications of ASA

  • Automotive: Exterior trim, mirror housings, and under-hood components.

  • Outdoor Fixtures: Garden tools, patio furniture, and UV-resistant signage.

  • Industrial: Jigs, enclosures, and chemical-resistant parts.

  • Consumer Goods: Durable phone cases, outdoor toys, and sporting equipment.

Requirements to Print ASA

  • Enclosure or warm ambient air

  • Not needed, but all-metal hotend is recommended if attempting to print above 240°C

Polymaker's ASA makes for great outdoor applications