Polymaker PC-ABS

1. Identification

JF Polymers (Suzhou) Co. Ltd Tel/Fax:

Haicheng Industrial Park, Bldg 7, +86- 512-52096516

Changshu Economic Development Zone +86- 512-52096512

(CEDZ)

Changshu, Jiangsu Province 215513

China

Product Name: Polymaker™ PC-ABS

Chemical Family: Thermoplastic Polymer

Use: 3D Printing Filament

  1. Hazards Identification

GHS Classification

This product is not hazardous in the form in which it is shipped by the manufacturer.

GHS Label Elements

Signal word: Warning

Hazard statements: If fine particles are generated during further processing, handling or by other means, product may form combustible dust concentrations in air.

  1. Composition/Information on Ingredients

Hazardous Components

There are no hazardous components above the relevant concentration limits according to OSHA HazCom 2012.

  1. First Aid Measures

Material Name: Polymaker™ PC-ABS 00855704

Most Important Symptom(s)/Effect(s)

Acute: Contact with heated material can cause thermal burns., Gases and fumes evolved during the thermal processing or decomposition of this material may irritate the eyes, skin or respiratory tract.

Eye Contact

In case of contact, flush eyes with plenty of lukewarm water.

Skin Contact

Cool melted product on skin with plenty of water. Do not remove solidified product. Get medical attention if thermal burn occurs.

Inhalation

Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion.

Ingestion Get medical attention. 5. Firefighting Measures

Suitable Extinguishing Media: Water fog, Dry chemical, Carbon dioxide (CO2), Foam

Unsuitable Extinguishing Media: High Pressure Water Streams

Fire Fighting Procedure

Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes.

Hazardous Decomposition Products By Fire and Thermal Decomposition: ; Phenol; Styrene; Acrylonitrile Carbon oxides, Hazardous decomposition products due to incomplete combustion

Unusual Fire/Explosion Hazards

Toxic and irritating gases/fumes may be given off during burning or thermal decomposition. Avoid generating dust: fine dust dispersed in air in sufficient concentrations and in the presence of an ignition source is a potential dust explosion hazard. 6. Accidental Release Measures Spill and Leak Procedures If molten, allow material to cool and place into an appropriate marked container for disposal. Sweep up and shovel into suitable containers for disposal. Dust deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture as they are released into the atmosphere in sufficient concentrations. Avoid dispersal of dust in the air (e.g., cleaning dust from surfaces with compressed air). 7. Handling and Storage

Material Name: Polymaker™ PC-ABS 00855704

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Handling/Storage Precautions

Handle in accordance with good industrial hygiene and safety practices. Wash thoroughly after handling. Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dust does not accumulate on surfaces. Solid particulate can generate electrical charging during operations such as unloading from containers and pneumatic transfer. Provide adequate precautions, such as electrical grounding and bonding, where conductive equipment is involved.

Storage Period:

None.

Storage Temperature

Maximum: 49 °C (120.2 °F)

Storage Conditions

Containers should be tightly closed to prevent contamination with foreign materials and moisture.

Substances to Avoid

None known.

The recommendations in this section should not be a substitute for a personal protective equipment (PPE) assessment performed by the employer as required by 29 CFR 1910 Subpart I.

Exposure Limits

Any component which is listed in section 3 and is not listed in this section does not have a known ACGIH TLV, OSHA PEL or supplier recommended occupational exposure limit.

Industrial Hygiene/Ventilation Measures

General dilution and local exhaust as necessary to control airborne vapors, mists, dusts and thermal decomposition products below appropriate airborne concentration standards/guidelines, especially during cutting, grinding and high heat operations.

Respiratory Protection

Although no exposure limit has been established for this product, the OSHA PEL for Particulates Not Otherwise Regulated (PNOR) of 15 mg/m3 - total dust, 5 mg/m3 - respirable fraction is recommended. In addition, the ACGIH recommends 3 mg/m3 - respirable particles and 10 mg/m3 - inhalable particles for Particles (insoluble or poorly soluble) Not Otherwise Specified (PNOS)., In the event that these limits are exceeded, an air purifying respirator (APR) equipped with particulate (P100) cartridges is recommended.

Hand Protection

Ensure gloves remain in good condition during use and replace if any deterioration is observed.

Wear heat resistant gloves when handling molten material.

Eye Protection

Safety glasses with side-shields

Skin Protection

No special skin protection requirements during normal handling and use.

Additional Protective Measures

Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees in the safe use and handling of this product. Purgings should be collected as small flat thin shapes or thin strands to allow for rapid cooling.

9. Physical and Chemical Properties

State of Matter: solid

Appearance: pellets

Color: Natural

Odor: Odorless

Odor Threshold: No Data Available

pH: No Data Available

Melting Point: 220 °C (428 °F)

Boiling Point: No Data Available

Flash Point: 320 °C (608 °F)

Evaporation Rate: No Data Available

Flammability: No Data Available

Lower Explosion Limit: No Data Available

Upper Explosion Limit: No Data Available

Vapor Pressure: No Data Available

Vapor Density: No Data Available

Density: ca. 1.1 - 1.2 g/cm³ (DIN 53479)

Relative Vapor Density: No Data Available

Specific Gravity: No Data Available

Solubility in Water: practically insoluble

Partition Coefficient: No Data Available

noctanol/water:

Auto-ignition Temperature: > 320 °C (> 608 °F)

Decomposition Temperature: >= 380 °C (716 °F)

Softening point: 100 - 200 °C (212 - 392 °F)

Dynamic Viscosity: not applicable

Kinematic Viscosity: No Data Available

Bulk Density: 600 - 700 kg/m3

  1. Stability and Reactivity

Hazardous Reactions

Hazardous polymerisation does not occur.

Stability

Stable

Materials to Avoid

None known.

Conditions to Avoid

Generation of dust clouds.

Material Name: Polymaker™ PC-ABS 00855704

Hazardous Decomposition Products

By Fire and Thermal Decomposition: Phenol; Styrene; Acrylonitrile; Carbon oxides, Hazardous decomposition products due to incomplete combustion

Likely Routes of Exposure: Inhalation

Skin Contact

Eye Contact

Health Effects and Symptoms

Acute: Contact with heated material can cause thermal burns., Gases and fumes evolved during the thermal processing or decomposition of this material may irritate the eyes, skin or respiratory tract.

Toxicity Data for: BAYBLEND T45PG 000000

No data available for this product.

Carcinogenicity:

No carcinogenic substances as defined by IARC, NTP and/or OSHA

  1. Ecological Information

Ecological Data for: BAYBLEND T45PG 000000

No data available for this product.

  1. Disposal Considerations

Waste Disposal Method

Waste disposal should be in accordance with existing federal, state and local environmental control laws.

  1. Transportation Information

Land transport (DOT)

Non-Regulated

Sea transport (IMDG)

Non-Regulated

Air transport (ICAO/IATA)

Non-Regulated

Material Name: Polymaker™ PC-ABS 00855704

15. Regulatory Information

United States Federal Regulations

US. Toxic Substances Control Act: Listed on the Active Portion of the TSCA Inventory.

No substances are subject to TSCA 12(b) export notification requirements.

US. EPA CERCLA Hazardous Substances (40 CFR 302) Components:

None

SARA Section 311/312 Hazard Categories:

Refer to hazard classification information in Section 2.

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A) Components: None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required Components: None

US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents (40 CFR 261):

Under RCRA, it is the responsibility of the person who generates a solid waste, as defined in 40 CFR 261.2,to determine if that waste is a hazardous waste.

State Right-To-Know Information

The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the SDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.

The concentrations reported below in units of parts per million (ppm) or parts per billion (ppb) are maximum values.

Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:

Concentration
Components
CAS-No.

$>=1%$

Polymer

CAS# is a trade secret

$>=1%$

Polymer

CAS# is a trade secret

$>=1%$

Bisphenol A Polycarbonate

CAS# is a trade secret

$>=1%$

Bisphenol A Polycarbonate

25971-63-5

$>=1%$

Bisphenol A Polycarbonate

CAS# is a trade secret

New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous Substances Lists:

Concentration Components CAS-No.

>=1% Polymer CAS# is a trade secret

Massachusetts Right to Know Extraordinarily Hazardous Substance List:

Concentration Components CAS-NO.

<=3 ppm Methylene Chloride 75-09-2

<=100ppm Acrylonitrile 107-13-1

<=0.1% Styrene 100-42-5

California Proposition 65 List:

Concentration
Components
CAS-No.

$<=100$ppm

Acrylonitrile

107-13-1

$<1ppt$

1,3-Butadiene

106-99-0

$<=3$ ppm

Methylene Chloride

75-09-2

Trace element

Bisphenol A

80-05-7

<0.1%

Styrene

100-42-5

CFATS (Chemical Facility Anti-Terrorism Standards) Chemicals

To the best of our knowledge, this product does not contain Appendix A Chemicals of Interest (COI), at or above the Screening Threshold Quantity (STQ), as defined by the Department of Homeland Security Chemical Facility Anti-terrorism Standard (CFATS, 6 CFR Part 27).

Based on information provided by our suppliers, this product is considered “DRC Conflict Free” as defined by the SEC Conflict Minerals Final Rule (Release No. 34-67716; File No. S7-40-10; Date: 2012-08-22).

16. Other Information

The method of hazard communication for Covestro LLC is comprised of product labels and safety data sheets. Safety data sheets for all of our products and general product declarations are available for download at www.productsafetyfirst.covestro.com.

Contact: Product Safety Department

Telephone: (412) 413-2835

SDS Number: 112000010508

Version Date: 12/18/2018

SDS Version: 2.7

Information contained in this SDS is believed to be accurate but is furnished without warranty, express or implied, including warranties of merchantability or fitness for a particular purpose. The information relates only to the specific material designated herein. Covestro LLC. assumes no legal responsibility for use of or reliance upon the information in this SDS and such information shall in no case be considered a part of our terms and conditions of sale. The user is responsible for determining whether the Covestro product is suitable for user’s method of use or application. Covestro is not liable for any failure to observe the precautionary measures described in this SDS or for any misuse of the product.

Changes since the last version are highlighted in the margin. This version replaces all previous versions.

Material Name: Polymaker™ PC-ABS
00855704

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